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西安交大-貝士德儀器

聯(lián)合實(shí)驗(yàn)室簡介

先進(jìn)吸附分離技術(shù) 聯(lián)合實(shí)驗(yàn)室成立于2019年，由西安交通大學(xué)化學(xué)工程與技術(shù)學(xué)院與貝士德儀器主導(dǎo)，以建立吸附分離領(lǐng)域國際領(lǐng)先水平的實(shí)驗(yàn)室為目標(biāo)。

目前“先進(jìn)吸附分離技術(shù)”聯(lián)合實(shí)驗(yàn)室已經(jīng)裝備多款國際先進(jìn)的吸附分離儀器設(shè)備，包括BSD-PS比表面積及孔徑分析儀，BSD-PM高性能比表面積及微孔分析儀，BSD-PMC腐蝕性氣體吸附分析儀，BSD-PH全自動(dòng)高溫高壓氣體吸附儀，BSD-VVS多站重量法真空蒸汽吸附儀，BSD-MAB多組分吸附穿透曲線分析儀，BSD-MASS在線質(zhì)譜氣體分析系統(tǒng)等。

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馬和平

西安交通大學(xué)化學(xué)工程與技術(shù)學(xué)院，特聘研究員，博士生導(dǎo)師，材料化工所副所長。省部級(jí)高層次人才青年項(xiàng)目，西安交通大學(xué)“青年拔尖人才”。

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楊慶遠(yuǎn)

西安交通大學(xué)化學(xué)工程與技術(shù)學(xué)院，教授，博士生導(dǎo)師，省部級(jí)高層次人才，西安交通大學(xué)“青年拔尖人才”，西安交通大學(xué)“青年教師跟蹤支持”計(jì)劃。

第1頁-11.PNG

柳劍峰

西安交大研究生院，校外合作特聘指導(dǎo)教師。貝士德儀器總經(jīng)理，總工程師。

研究成果匯總

西交大化工學(xué)院-貝士德儀器?先進(jìn)吸附分離技術(shù) 聯(lián)合實(shí)驗(yàn)室?近一年多時(shí)間，在國際和國內(nèi)期刊上共發(fā)表學(xué)術(shù)論文約18篇，包括Angewandte Chemie，Chemical Engineering Journal，ACS Catalysis，ACS Nano，Chem. Eng. J.，J. Mater. Chem. A 等,其中影響因子大于10的有?9?篇，JCR一區(qū)文章?15?篇。研究領(lǐng)域?涉及質(zhì)子傳導(dǎo)、二氧化硫和芳香族硫化物捕獲、煙氣脫硫耦合脫碳、煙道氣中SO2捕集、電子特氣（SF6、NF3、CF4、Xe、Kr等）分離、煤層氣分離、溫室氣體六氟化硫捕獲（SF₆、CF₄、NF₃等）、烷烯烴分離、光催化CO2還原等多個(gè)領(lǐng)域。以下例舉“先進(jìn)吸附分離技術(shù)”聯(lián)合實(shí)驗(yàn)室近年發(fā)表的部分精彩文章：

例舉文章 1
兩性離子共價(jià)有機(jī)骨架：有吸引力的多孔主體用于氣體分離及無水質(zhì)子傳導(dǎo)

該研究成果以“Zwitterionic Covalent Organic Frameworks: Attractive Porous Host for Gas Separation and Anhydrous Proton Conduction”（兩性離子共價(jià)有機(jī)骨架：有吸引力的多孔主體用于氣體分離及無水質(zhì)子傳導(dǎo)）為題發(fā)表于國際權(quán)威期刊《美國化學(xué)會(huì)-納米》（ACS Nano）上，影響因子15.881。西安交通大學(xué)化學(xué)工程與技術(shù)學(xué)院為本文的唯一單位，博士生傅鈺為論文第一作者，馬和平研究員為唯一通訊作者。

本研究工作以共價(jià)有機(jī)骨架（COF）為功能性平臺(tái)，同時(shí)將陰、陽離子官能團(tuán)引入到COF孔道中，實(shí)現(xiàn)了兩性離子概念與多孔結(jié)晶材料的結(jié)合。兩性離子COF內(nèi)同時(shí)具備陰、陽離子位點(diǎn)排列的結(jié)構(gòu)能夠?qū)崿F(xiàn)在納米通道內(nèi)的電荷密度調(diào)節(jié)，允許對(duì)其結(jié)構(gòu)和功能進(jìn)行原子水平調(diào)控，這給設(shè)計(jì)具備功能導(dǎo)向的材料提供了新的思路。文中設(shè)計(jì)并合成了三種兩性離子COF材料，作為多孔主體在SO₂/CO₂氣體分離及無水質(zhì)子傳導(dǎo)領(lǐng)域均展現(xiàn)出極大的應(yīng)用潛力。兩性離子COF孔道內(nèi)分散的正、負(fù)電荷基團(tuán)可以作為SO₂的兩種不同的極性位點(diǎn)，使其實(shí)現(xiàn)了高SO₂吸附量及突出的SO₂/CO₂分離性能。此外，相反電荷片段的組合賦予了兩性離子COF豐富的離子遷移位點(diǎn)，使其在負(fù)載三氮唑、咪唑后實(shí)現(xiàn)了優(yōu)異的質(zhì)子傳導(dǎo)性能。理論計(jì)算與介電常數(shù)分析相結(jié)合，證實(shí)了COF孔道內(nèi)陽離子和陰離子基團(tuán)的存在能夠有效促進(jìn)質(zhì)子載體中質(zhì)子的釋放。我們相信兩性離子在COF材料中的成功結(jié)合可以為COF的各種應(yīng)用提供無限的可能。

圖 . (a) 離子型聚合物、兩性離子型聚合物、離子型COFs和兩性離子型COFs示意圖；(b) 三種不同結(jié)構(gòu)的兩性離子型COFs合成示意圖（注：陰離子和陽離子位點(diǎn)分別用藍(lán)色和黃色標(biāo)記）。

例舉文章 2
具有創(chuàng)紀(jì)錄CH4/N2分離比的鎳基MOF材料用于煤層氣分離

該研究成果以?“Nickel-Based Metal–Organic Frameworks for Coal-Bed Methane Purification with Record CH4/N2 Selectivity” 為題發(fā)表于國際知名期刊《德國應(yīng)用化學(xué)》(Angew. Chem. Int. Ed.)(IF=15.336)上，并被選為Angewandte Chemie 封面文章和熱點(diǎn)論文?；瘜W(xué)工程與技術(shù)學(xué)院博士生王少敏為論文第一作者，楊慶遠(yuǎn)教授為本文通訊作者，西安交通大學(xué)化工學(xué)院為論文唯一通訊作者單位。

實(shí)現(xiàn)雙碳目標(biāo)，天然氣是目前最現(xiàn)實(shí)的低碳清潔能源，但我國常規(guī)天然氣產(chǎn)能不足，需開發(fā)煤層氣等非常規(guī)天然氣作為補(bǔ)充。煤層氣俗稱“瓦斯”，其主要成分是甲烷，是一種與煤共生、以吸附態(tài)存儲(chǔ)于煤層內(nèi)的非常規(guī)天然氣，我國煤層氣儲(chǔ)量豐富，2020年探明的儲(chǔ)量約為4200億立方米。但超過70%的煤層氣在開采時(shí)，由于開采技術(shù)（井下抽采）的原因混入了大量的空氣，導(dǎo)致形成了低濃度的煤層氣（甲烷濃度＜30%）而得不到很好的利用，低濃度的煤層氣一般被直接排放到大氣，造成了資源浪費(fèi)和溫室效應(yīng)。所以現(xiàn)階段煤層氣的分離與提濃技術(shù)已成為煤層氣開發(fā)和利用的行業(yè)瓶頸問題，是需要攻克的關(guān)鍵節(jié)點(diǎn)。針對(duì)上述問題，西安交通大學(xué)化工學(xué)院楊慶遠(yuǎn)教授課題組研發(fā)了系列鎳基-金屬有機(jī)框架（MOF）材料，其中超微孔MOF材料Ni(ina)₂具有甲烷/氮?dú)膺x擇性高（15.8）、吸附容量大（46.7 cm³/g）和分子擴(kuò)散速率快（10.6-19.0 cm3g^-1s^-1）的特點(diǎn),較好地解決了氣體分離領(lǐng)域的“trade-off”效應(yīng)，實(shí)現(xiàn)了煤層氣中甲烷和氮?dú)獾母咝Х蛛x。理論模擬計(jì)算和單晶結(jié)構(gòu)解析表明Ni(ina)2和甲烷分子之間存在較強(qiáng)的作用力，可以從低濃度煤層氣中選擇性地捕獲甲烷分子。另外，Ni(ina)2具有很好的熱穩(wěn)定性和化學(xué)穩(wěn)定性，可以批量化制備，是一種理想的固體吸附劑，該工作為工業(yè)上煤層氣的分離提供了新思路。

更多精彩

Zwitterionic Covalent Organic Frameworks: Attractive Porous Host for Gas Separation and Anhydrous Proton Conduction

ACS Nano??(IF = 18.027)

https://doi.org/10.1021/acsnano.1c07178

Tuning proton dissociation energy in proton carrier doped 2D covalent organic frameworks for anhydrous proton conduction at elevated temperature

J. Mater. Chem. A???(IF = 14.511)

https://doi.org/10.1039/D0TA04488A

A 3D ultramicroporous porous organic frameworks for SO2 and aromatic sulfides capture with high capacity and selectivity

Chemical Engineering Journal?(IF = 16.744)

https://doi.org/10.1016/j.cej.2021.132480

離子型有機(jī)多孔聚合物的制備及其煙氣脫硫耦合脫碳性質(zhì)研究

《化工進(jìn)展》

https://doi.org/10.16085/j.issn.1000-6613.2022-0689

Post modification of Oxo-clusters in robust Zirconium-Based metal organic framework for durable SO2 capture from flue gas

Separation and Purification Technology???(IF = 9.136)

https://doi.org/10.1016/j.seppur.2021.119349

Aliphatic amine decorating metal–organic framework for durable SO2 capture from flue gas

Separation and Purification Technology??(IF = 9.136)

https://doi.org/10.1016/j.seppur.2020.118164

Tuning surface inductive electric field in microporous organic polymers for Xe/Kr separation

Chemical Engineering Journal???(IF = 16.744)

https://doi.org/10.1016/j.cej.2021.131271

Enhancing Perfluorinated electron specialty gases separation selectivity in ultra-microporous metal organic framework

Separation and Purification Technology??( IF = 9.136)

https://doi.org/10.1016/j.seppur.2022.120739

Adsorption Interface-Induced H...F Charge Transfer in Ultramicroporous Metal-Organic Frameworks for Perfluorinated Gas Separation

Industrial & Engineering Chemistry Research??(IF = 4.326)

https://doi.org/10.1021/acs.iecr.2c01604

?

HF Resistant Porous Aromatic Frameworks for Electronic Special Gases Separation

Langmuir???(IF = 4.311)

https://doi.org/10.1021/acs.langmuir.2c01098

Fluorine-functionalized Porous Organic Polymers for Durable F-gas Capture from Semiconductor Etching Exhaust

Macromolecules??(IF = 6.057)

https://doi.org/10.1021/acs.macromol.1c02413

Fluorinated porous organic polymers for efficient recovery perfluorinated electronic specialty gas from exhaust gas of plasma etching

Separation and Purification Technology???(IF = 9.136)

https://doi.org/10.1016/j.seppur.2022.120561

Fluorine-Induced Electric Field Gradient in 3D Porous Aromatic Frameworks for Highly Efficient Capture of Xe and F-Gases

ACS Appl. Mater. Interfaces???(IF = 10.383)

https://doi.org/10.1021/acsami.2c10050

Pore-Structure Control in Metal–Organic Frameworks (MOFs) for Capture of the Greenhouse Gas SF6 with Record Separation

Angew. Chem. Int. Ed.?(IF = 16.82)?

https://doi.org/10.1002/anie.202207066

?

Nickel-Based Metal–Organic Frameworks for Coal-Bed Methane Purification with Record CH4/N2 Selectivity

Angew. Chem. Int. Ed.??(IF = 16.82)?

https://doi.org/10.1002/ange.202201017

Amino-functionalized microporous MOFs for greenhouse gases CF4 and NF3 capture with record selectivity

ACS Applied Materials & Interfaces??(IF=10.38)

https://pubs.acs.org/doi/abs/10.1021/acsami.2c12164

?

Control of pore structure by the solvent effect for efficient ethane/ethylene separation

Separation and Purification Technology??(IF=9.13)

https://www.sciencedirect.com/science/article/pii/S1383586622019335

?

Immobilizing Isatin-Schiff Base Complexes in NH2-UiO-66 for Highly?Photocatalytic CO2 Reduction

ACS Catalysis ?(IF=13.7)

https://pubs.acs.org/doi/10.1021/acscatal.2c04588

測(cè)試數(shù)據(jù)摘錄

Zwitterionic Covalent Organic Frameworks: Attractive Porous Host for Gas Separation and Anhydrous Proton Conduction

ACS Nano??(IF = 18.027)

https://doi.org/10.1021/acsnano.1c07178

Tuning proton dissociation energy in proton carrier doped 2D covalent organic frameworks for anhydrous proton conduction at elevated temperature

J. Mater. Chem. A???(IF = 14.511)

https://doi.org/10.1039/D0TA04488A

A 3D ultramicroporous porous organic frameworks for SO2 and aromatic sulfides capture with high capacity and selectivity

Chemical Engineering Journal?(IF = 16.744)

https://doi.org/10.1016/j.cej.2021.132480

離子型有機(jī)多孔聚合物的制備及其煙氣脫硫耦合脫碳性質(zhì)研究

《化工進(jìn)展》

https://doi.org/10.16085/j.issn.1000-6613.2022-0689

Post modification of Oxo-clusters in robust Zirconium-Based metal organic framework for durable SO2 capture from flue gas

Separation and Purification Technology???(IF = 9.136)

https://doi.org/10.1016/j.seppur.2021.119349

Aliphatic amine decorating metal–organic framework for durable SO2 capture from flue gas

Separation and Purification Technology??(IF = 9.136)

https://doi.org/10.1016/j.seppur.2020.118164

Tuning surface inductive electric field in microporous organic polymers for Xe/Kr separation

Chemical Engineering Journal???(IF = 16.744)

https://doi.org/10.1016/j.cej.2021.131271

Enhancing Perfluorinated electron specialty gases separation selectivity in ultra-microporous metal organic framework

Separation and Purification Technology??( IF = 9.136)

https://doi.org/10.1016/j.seppur.2022.120739

Adsorption Interface-Induced H...F Charge Transfer in Ultramicroporous Metal-Organic Frameworks for Perfluorinated Gas Separation

Industrial & Engineering Chemistry Research??(IF = 4.326)

https://doi.org/10.1021/acs.iecr.2c01604

?

HF Resistant Porous Aromatic Frameworks for Electronic Special Gases Separation

Langmuir???(IF = 4.311)

https://doi.org/10.1021/acs.langmuir.2c01098

Fluorine-functionalized Porous Organic Polymers for Durable F-gas Capture from Semiconductor Etching Exhaust

Macromolecules??(IF = 6.057)

https://doi.org/10.1021/acs.macromol.1c02413

Fluorinated porous organic polymers for efficient recovery perfluorinated electronic specialty gas from exhaust gas of plasma etching

Separation and Purification Technology???(IF = 9.136)

https://doi.org/10.1016/j.seppur.2022.120561

Fluorine-Induced Electric Field Gradient in 3D Porous Aromatic Frameworks for Highly Efficient Capture of Xe and F-Gases

ACS Appl. Mater. Interfaces???(IF = 10.383)

https://doi.org/10.1021/acsami.2c10050

Pore-Structure Control in Metal–Organic Frameworks (MOFs) for Capture of the Greenhouse Gas SF6 with Record Separation

Angew. Chem. Int. Ed.?(IF = 16.82)?

https://doi.org/10.1002/anie.202207066

?

Nickel-Based Metal–Organic Frameworks for Coal-Bed Methane Purification with Record CH4/N2 Selectivity

Angew. Chem. Int. Ed.??(IF = 16.82)?

https://doi.org/10.1002/ange.202201017

Amino-functionalized microporous MOFs for greenhouse gases CF4 and NF3 capture with record selectivity

ACS Applied Materials & Interfaces??(IF=10.38)

https://pubs.acs.org/doi/abs/10.1021/acsami.2c12164

?

Control of pore structure by the solvent effect for efficient ethane/ethylene separation

Separation and Purification Technology??(IF=9.13)

https://www.sciencedirect.com/science/article/pii/S1383586622019335

?

Immobilizing Isatin-Schiff Base Complexes in NH2-UiO-66 for Highly?Photocatalytic CO2 Reduction

ACS Catalysis ?(IF=13.7)

https://pubs.acs.org/doi/10.1021/acscatal.2c04588

測(cè)試數(shù)據(jù)摘錄

Zwitterionic Covalent Organic Frameworks: Attractive Porous Host for Gas Separation and Anhydrous Proton Conduction

ACS Nano??(IF = 18.027)

Tuning proton dissociation energy in proton carrier doped 2D covalent organic frameworks for anhydrous proton conduction at elevated temperature

A 3D ultramicroporous porous organic frameworks for SO2 and aromatic sulfides capture with high capacity and selectivity

Chemical Engineering Journal?(IF = 16.744)

離子型有機(jī)多孔聚合物的制備及其煙氣脫硫耦合脫碳性質(zhì)研究

Post modification of Oxo-clusters in robust Zirconium-Based metal organic framework for durable SO2 capture from flue gas

Aliphatic amine decorating metal–organic framework for durable SO2 capture from flue gas

Tuning surface inductive electric field in microporous organic polymers for Xe/Kr separation

Chemical Engineering Journal???(IF = 16.744)

Enhancing Perfluorinated electron specialty gases separation selectivity in ultra-microporous metal organic framework

Adsorption Interface-Induced H...F Charge Transfer in Ultramicroporous Metal-Organic Frameworks for Perfluorinated Gas Separation

Industrial & Engineering Chemistry Research??(IF = 4.326)

?

HF Resistant Porous Aromatic Frameworks for Electronic Special Gases Separation

Langmuir???(IF = 4.311)

Fluorine-functionalized Porous Organic Polymers for Durable F-gas Capture from Semiconductor Etching Exhaust

Macromolecules??(IF = 6.057)

https://doi.org/10.1021/acs.macromol.1c02413

Fluorinated porous organic polymers for efficient recovery perfluorinated electronic specialty gas from exhaust gas of plasma etching

Separation and Purification Technology???(IF = 9.136)

https://doi.org/10.1016/j.seppur.2022.120561

Fluorine-Induced Electric Field Gradient in 3D Porous Aromatic Frameworks for Highly Efficient Capture of Xe and F-Gases

ACS Appl. Mater. Interfaces???(IF = 10.383)

Pore-Structure Control in Metal–Organic Frameworks (MOFs) for Capture of the Greenhouse Gas SF6 with Record Separation

Angew. Chem. Int. Ed.?(IF = 16.82)?

?

Nickel-Based Metal–Organic Frameworks for Coal-Bed Methane Purification with Record CH4/N2 Selectivity

Angew. Chem. Int. Ed.??(IF = 16.82)?

Amino-functionalized microporous MOFs for greenhouse gases CF4 and NF3 capture with record selectivity

?

Control of pore structure by the solvent effect for efficient ethane/ethylene separation

?

Immobilizing Isatin-Schiff Base Complexes in NH2-UiO-66 for Highly?Photocatalytic CO2 Reduction

相關(guān)內(nèi)容：

Zwitterionic Covalent Organic Frameworks: Attractive Porous Host for Gas Separation and Anhydrous Proton Conduction

ACS Nano??(IF = 18.027)

Tuning proton dissociation energy in proton carrier doped 2D covalent organic frameworks for anhydrous proton conduction at elevated temperature

A 3D ultramicroporous porous organic frameworks for SO2 and aromatic sulfides capture with high capacity and selectivity

Chemical Engineering Journal?(IF = 16.744)

離子型有機(jī)多孔聚合物的制備及其煙氣脫硫耦合脫碳性質(zhì)研究

Post modification of Oxo-clusters in robust Zirconium-Based metal organic framework for durable SO2 capture from flue gas

Aliphatic amine decorating metal–organic framework for durable SO2 capture from flue gas

Tuning surface inductive electric field in microporous organic polymers for Xe/Kr separation

Chemical Engineering Journal???(IF = 16.744)

Enhancing Perfluorinated electron specialty gases separation selectivity in ultra-microporous metal organic framework

Adsorption Interface-Induced H...F Charge Transfer in Ultramicroporous Metal-Organic Frameworks for Perfluorinated Gas Separation

Industrial & Engineering Chemistry Research??(IF = 4.326)

?

HF Resistant Porous Aromatic Frameworks for Electronic Special Gases Separation

Langmuir???(IF = 4.311)

Fluorine-functionalized Porous Organic Polymers for Durable F-gas Capture from Semiconductor Etching Exhaust

Macromolecules??(IF = 6.057)

https://doi.org/10.1021/acs.macromol.1c02413

Fluorinated porous organic polymers for efficient recovery perfluorinated electronic specialty gas from exhaust gas of plasma etching

Separation and Purification Technology???(IF = 9.136)

https://doi.org/10.1016/j.seppur.2022.120561

Fluorine-Induced Electric Field Gradient in 3D Porous Aromatic Frameworks for Highly Efficient Capture of Xe and F-Gases

ACS Appl. Mater. Interfaces???(IF = 10.383)

Pore-Structure Control in Metal–Organic Frameworks (MOFs) for Capture of the Greenhouse Gas SF6 with Record Separation

Angew. Chem. Int. Ed.?(IF = 16.82)?

?

Nickel-Based Metal–Organic Frameworks for Coal-Bed Methane Purification with Record CH4/N2 Selectivity

Angew. Chem. Int. Ed.??(IF = 16.82)?

Amino-functionalized microporous MOFs for greenhouse gases CF4 and NF3 capture with record selectivity

?

Control of pore structure by the solvent effect for efficient ethane/ethylene separation

?

Immobilizing Isatin-Schiff Base Complexes in NH2-UiO-66 for Highly?Photocatalytic CO2 Reduction

相關(guān)內(nèi)容：